![]() The enhanced catalytic performance of the bifunctional catalyst with hierarchical SAPO-34 could be attributed to the hierarchical structure of SAPO-34 that can increase the rate of mass transfer to avoid further hydrogenation and conversion of olefin products on the catalyst, thus could improve the selectivity of C2–C4 olefins. ![]() Importantly, the bifunctional catalyst with hierarchical SAPO-34 has a good catalytic stability with no obvious deactivation over 100 h of testing. Compared with the bifunctional catalyst obtained from the SAPO-34 molecular sieves without post-treatment, the bifunctional catalyst with hierarchical SAPO-34 obtained by mother liquor post-treatment showed enhanced performance with higher selectivity of light olefins. The obtained hierarchical SAPO-34 were mixed with ZnCrAlOx oxide to prepare the bifunctional catalyst, and the catalytic performance for direct conversion of syngas to light olefins was examined. The physical and chemical properties of the resulting molecular sieves were characterized by XRD, SEM, TEM, N2 adsorption–desorption, XRF and NH3-TPD. In this study, we present a facile post-treatment approach to obtain hierarchical SAPO-34 by treating the crystallized product in mother liquor at low temperature. The designed capsule catalyst has superior potential for scale-up in the industrial application, at the same time extending the horizontal of hybrid catalysts for other tandem catalysis reactions through this strategy.ĭirect synthesis of light olefins from syngas (STO) using bifunctional catalyst composed of oxide and zeolite has attracted extensive attention in both academia and industry. The light olefins space time yield (STY) of the capsule catalyst is beyond twice of that of the typical physical mixture catalyst. Due to the difference between the adsorption energies of Zn-Cr metallic oxide/SAPO zeolite physical mixture and capsule catalysts, the formed water and light olefins are easily removed in the capsule catalyst after formation, suppressing the side reactions. The confinement effect, hierarchical structure and extremely short distance between the two active components realize this capsule catalyst having better mass transfer and diffusion with boosted synergic effect. It can not only break through the limitation of Anderson-Schulz-Flory distribution but also overcome the disadvantages in the physical mixture catalysts such as the plenty of CO2 formation. An elegant catalyst is designed via encapsulation of the metallic oxide Zn-Cr inside of zeolite SAPO34 as a core-shell structure to realize the coupling of methanol-synthesis and methanol-to-olefins reactions.
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5/5/2023 0 Comments Ka quiri agot![]() In CK2, players battle against other rulers for control of various independent realms and kingdoms. What makes this mod different from Crusader Kings II?īesides the obvious, which is a new interactive rendition of the fictional low-fantasy medieval setting of ASoIaF, you’ll notice a host of changes that build off the framework of the original (vanilla) CK2 game. Currently players are able to choose to play from any start date in the 300 years from before the Aegon's Conquest to the beginning of the fourth book ( A Feast for Crows). The mod takes its name from the first book in the series, as well as the “game” of plots and politics the ambitious and hopeful are said to be playing in their struggles for supremacy. ![]() Martin’s A Song of Ice and Fire ( ASoIaF) fantasy saga where lords great and small vie for control over the lands of Ice and Fire, from Westeros and the Seven Kingdoms in the west, to Qarth in the east. (3) in short, the AGOT mod is a much more fleshed out game in a time period better known to most, but the TSK mod has a way better map and I think will be a better mod in the long run as features come out.“A Game of Thrones” ( AGOT) is a full-conversion mod for Paradox Interactive’s Crusder Kings II (CK2). EDIT: The TSK mod is also way more stable. ![]() The mechanics they currently have work really well, and the ones that are coming will make it a superb mod. The map is stunning, and it’s also vast (having dozens of provinces in the Iron Islands alone, for example, is something I love the map is so large you could play a whole campaign just trying to conquer one of the Seven Kingdoms). (2) That said, the TSK mod is also amazing as far as I’m concerned, and that’s despite the devs saying it’s still an alpha. If you like playing in the timeline of the books, this is definitely for you (in one game as Robert Baratheon I quickly found our Cercei was planning to murder me, so I had her and Jamie imprisoned and executed, and took young Tyrion as a ward when Tywin rebelled, I quickly crushed him, executed him, and made sure Tyrion, as Lord of the Westerlands and Warden of the West, was a key asset in giving Westeros a bright future instead of endless war). (1) the AGOT mod is amazing, fleshed out, and with an incredibly wide array of special mechanics they have made for the mod. that don’t exist during the Age of Petty Kings), they already have a number of unique artifacts (think Valyrian steel weapons), and the devs have long discussed adding in lots of other features (including dragons, a market system, and variations on many of the other features in the AGOT mod). (2) the TSK mod has a cool resource system (think EUIV) where each province has a resource (or two or three) that affect the province in special ways, they have adapted the off map China system from vanilla to stand in for the Freehold of Valyria, they are about to add 100+ unique buildings all over the map, they already have special buildings you can develop over time (like Dragonstone, Sunspear, etc. (1) the AGOT mod undoubtedly has more features, including dragons, bloodlines (although I assume that will change with CKII releasing their own official version of bloodlines), knighthoods, squires, direworlves, The Citadel, septons, etc. (2) the devs for TSK mod plan to add other dates up through the Doom of Valyria, which would probably have the Targaryens on Dragonstone getting ready to launch their invasion. (1) The AGOT mod focuses heavily on “recent” history (the time period from the books and the century or so before the books), while the TSK mod focuses on the Age of Petty Kings (during the Andal invasion) and the Age of Heroes (think the mythical Bran the Builder, Lann the Cleaver, etc.) however (4) the map in the TSK mod is much nicer/more detailed/looks substantially better.people like different things in their CKII maps, but imo the TSK map looks much better than the AGOT map, which is what drew me to TSK mod in the first place (I’m a sucker for pretty maps). (3) because the TSK map only includes a small slice of Essos, Westeros has way more provinces and feels way more realistic and finally (2) both mods have roughly the same number of provinces (nearly 1,500) but (1) the TSK mod includes all of Westeros and only a sliver of western Essos (basically just the Free Cities), while the AGOT mod includes all of known Essos in addition to Westeros ![]() Both mods are aware of each other but will not be using resources from each other. Martin’s A Song of Ice and Fire series (and other works) are set. I’ve seen a few folks ask about this a while back, in archived posts, and haven’t really seen serious answers about the differences between both mods.įirst, both mods are set in the world where G.R.R. 5/5/2023 0 Comments Macbooster 8 keyEnjoy using MacBooster 2018 Full Version free for lifetime.Or use MacBooster License Key for manual activation.Run MacBooster Crack Full Free as administrator.Now extract the Crack file from download folder after completion of installation process.Install the program as installed others software.Download MacBooster Crack Free from links shared below.How to install & activate MacBooster Crack? System Requirements: OS: Windows XP, Vista, 7, 8, 8. You can also batch uninstall apps to save your time. Amardas - Servant of the imperishable one. MacBooster 7 Keygen will accurately find every app application folder on your Mac and the hidden parts of them, and then uninstall them with no leftovers. Spiritual name? 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MacBooster 8 License Key is a simple yet effective software that makes it very easy to clean and optimize your Mac and to guard your privacy and protection. ![]() # Later, launch the model, initialize the variables, do some work, and save the # Add ops to save and restore all the variables. Init_op = tf.global_variables_initializer() V2 = tf.get_variable("v2", shape=, initializer = tf.zeros_initializer) V1 = tf.get_variable("v1", shape=, initializer = tf.zeros_initializer) ![]() TensorFlow APIs).įrom the docs: Save # Create some variables. They are thus suitable for deployment via TensorFlow Serving, TensorFlow Lite, TensorFlow.js, or programs in other programming languages (the C, C++, Java, Go, Rust, C# etc. Models in this format are independent of the source code that created the model. The SavedModel format on the other hand includes a serialized description of the computation defined by the model in addition to the parameter values (checkpoint). ![]() Checkpoints do not contain any description of the computation defined by the model and thus are typically only useful when source code that will use the saved parameter values is available. Print("Restored from ".format(manager.latest_checkpoint))Įxhaustive and useful tutorial on saved_model -> Ĭheckpoints capture the exact value of all parameters (tf.Variable objects) used by a model. Manager = tf.train.CheckpointManager(ckpt, "./tf_ckpts", max_to_keep=3) Step=tf.Variable(1), optimizer=opt, net=net, iterator=iterator Optimizer.apply_gradients(zip(gradients, variables)) Loss = tf.reduce_mean(tf.abs(output - example)) """Trains `net` on `example` using `optimizer`.""" Tf._tensor_slices(dict(x=inputs, y=labels)).repeat().batch(2) This and some more advanced use-cases have been explained very well here.Ī quick complete tutorial to save and restore Tensorflow modelsĪdapted from the docs #. Op_to_restore = graph.get_tensor_by_name("op_to_restore:0") #Now, access the op that you want to run. # Now, let's access and create placeholders variables and # This will print 2, which is the value of bias that we saved Saver.restore(sess,tf.train.latest_checkpoint('./')) Saver = tf.train.import_meta_graph('my_test_ta') #First let's load meta graph and restore weights Restore the model: import tensorflow as tf Saver.save(sess, 'my_test_model',global_step=1000) #Create a saver object which will save all the variables W4 = tf.multiply(w3,b1,name="op_to_restore") #Define a test operation that we will restore I am improving my answer to add more details for saving and restoring models. ![]() In the Firefox DevTools you can also inspect the objects. Inspect object properties ¶īy clicking on an object logged within the console you can inspect the object’s properties and methods within the DOM panel. The command history available through a button in Firebug’s command line, is available by pressing ↑/ ↓ within the DevTools command line. This functionality is already integrated into the DevTools using the ChromeLogger protocol and doesn’t require any extensions to be installed. ![]() Server logs ¶įirebug extensions like FirePHP allow to log server-side messages to the Firebug console. In the DevTools this option is called Enable persistent logs and is available within the Toolbox Options panel. In Firebug you can click the Persist button within the toolbar to keep the logged messages between page navigations and reloads. The Developer Tools share the same API, so your console.* statements will continue to work. To log things to the console from within the web page Firebug makes a Console API available within the page. The Developer Tools command line has some functions in common, but also has some other functions and misses others. The Command Line API in Firebug provides some special functions for your convenience. The Developer Tools console offers similar functionality via the filter buttons inside its toolbar - centralized at one place. Filter log messages ¶įirebug offers two ways to filter log messages, via the options menu and via the filter buttons within the toolbar. The display between both is somewhat different. It shows log information associated with a web page and allows you to execute JavaScript expressions via its command line. The Web Console is the equivalent of Firebug’s Console panel. the Network Monitor can be opened via Ctrl + Shift + Q / Cmd + Opt + Q, the Web Console via Ctrl + Shift + K / Cmd + Opt + K and the Debugger via Ctrl + Shift + S / Cmd + Opt + S. The DevTools share the same shortcuts, but also provide shortcuts for the different panels. To open it to inspect an element it is possible to press Ctrl + Shift + C / Cmd + Opt + C. Open the tools ¶įirebug can be opened by pressing F12. When you switch to another tab, though, they’re closed. That means, that when you open the DevTools in a tab, they stay open even when you switch between different websites. The DevTools’ activation on the other hand is tab based. And when you open a page of a different origin in the same tab, it closes automatically. That means that when you open a page on the same origin in a different tab, Firebug gets opened automatically. Download Firefox Developer Edition General ¶ Activation ¶įirebug’s activation is URL based respecting the same origin policy. The following list aims to help Firebug users to find their way into the Developer Tools.įor the latest developer tools and features, try Firefox Developer Edition. ![]() When migrating from Firebug to the Firefox Developer Tools, you may wonder where the features you loved in Firebug are available in the Developer Tools.
5/4/2023 0 Comments Author of invisible emmie![]() ![]() Reading Invisible Emmie sums up middle school: You laugh, you cry, you get beaned in the head with a volleyball." - Stephan Pastis, author of Timmy Failure "In her first children's book, cartoonist Libenson offers strikingly different visions of seventh grade through two very dissimilar narrators. Invisible Emmie is unforgettable!" - Lincoln Peirce, author of Big Nate "This funny and heartfelt tale will ring true for anyone who's ever felt invisible." - Victoria Jamieson, Newbery Honor author-illustrator of Roller Girl "Clever, funny work by a great cartoonist. A fantastic debut novel with plenty of laughs and tons of heart. Invisible Emmie is unforgettable!, "This is middle grade fiction at its best. Reading INVISIBLE EMMIE sums up middle school: You laugh, you cry, you get beaned in the head with a volleyball., This is middle grade fiction at its best. ![]() Reading Invisible Emmie sums up middle school: You laugh, you cry, you get beaned in the head with a volleyball., With all-too-familiar middle-school drama and an empowering lesson about speaking up andbravely facing down embarrassment, this should find an easy audience among fans of Wimpy Kid or Dork Diaries books., Clever, funny work by a great cartoonist. Clever, funny work by a great cartoonist. 5/4/2023 0 Comments Best quick invoice factoringTo secure invoice financing, you’ll head to your bank and ask for quick access to money and show invoices proving you expect $5000 from clients in the near future. How are you going to pay for all of that now? But your outstanding invoices of $5,000 aren’t due for another 3 weeks. Let's say your business needs some quick cash flow to pay for operations, general overhead, and some payroll. ![]() Since your invoices serve as "collateral," you won't need to put up any other valuable assets for stake. You won't be owing weekly payments on the invoices financed, instead you'll just repay the due balance at once when your client pays you. ![]() Your total costs for invoice financing is most often based on a weekly basis, ranging from 0.5% to about 3% depending on how long your invoice is outstanding after taking the loan. It's typically around 3%, and comes out of the remaining 10% - 15% that you collect when balances are repaid. This is the flat fee a borrower must pay the invoice financing institution to facilitate the cash advance (similar to an origination fee on term loans). This type of financing is more expensive because the institution is taking a higher risk. However, with non-recourse factoring loans you are not responsible for making payment should your client fail to pay the invoice you have borrowed against. With recourse financing, you are liable to pay back the loan to the lending financial institution whether your client pays the invoice or not. Here are some important things to remember with invoice financing: The unpaid customer invoices serve as proof that you’ll have cash to pay the loan back in due time. Of course, the lender tacks on a fee (usually a % of the loan) for you to pay in exchange for their supply of capital. We’ll also explore an alternative you may not have considered.Īlso called accounts receivable financing, invoice financing is when a company gets a cash advance from a financial institution (e.g. In this article, we'll cover everything you need to know about invoice financing – including the different types, the pros and cons, and how you can qualify and apply. The costs are closing in but your money is still weeks out.Īside from turning to personal finances or asking friends and family for money, small business owners can consider invoice financing as a way to meet short-term business expenses. It can cause a lot of stress for small business owners, especially those in the B2B (business-to-business) space because of longer billing cycles. ![]() It covers your expenses, helps you find new customers and keep up with-or leave behind-the competition. Cash flow is something every business will closely monitor. ![]() ![]() The Coinbase platform provides customers with the ability to trade digital currencies for fiat money or other digital currencies on its Global Digital Asset Exchange (GDAX). It has become the most popular way to exchange Bitcoin, Ethereum, Litecoin, and other cryptocurrencies. ![]() Recently it has announced that it has raised $300 million dollars from some of the most prestigious American VCĬoinbase is a cryptocurrency exchange that was founded in 2012. Coinbase has been selected by IBM for its new Blockchain solution for global finance that will initially focus on cross-border payments between large companies. It is also one of the first crypto exchanges to offer trading of many digital assets, as well as the only crypto exchange to offer fiat currency-to-crypto trading pairs on major stock exchanges. It’s awesome that you can trade without worrying about paying tons of money in fees like you would on other exchanges like Coinbase orīinance is the best cryptocurrency exchange out there because of the following reasons:Ĭoinbase became the first regulated crypto exchange to offer listing on major stock exchanges. Fees are so low that they are almost non-existent. The first thing I want to talk about with Binance is how it has one of the lowest trading fees out there. So he created an exchange that would have cold storage wallets for all coins, strong encryption for two-factor authentication, and storing coins offline. I have used other exchanges in the past but Binance always seems to be the best option.īinance was founded by Changpeng Zhao who wanted to fix what he saw as a major issue with cryptocurrency exchanges – lack of security. You can buy BTC on binance and then find the BTC/SAND trading pair as simple as that!īinance is the best cryptocurrency exchange out there because of its low fees, good customer service, and security. The rest was allocated to company reserves, founder shares, staking rewards, and Binance Launchpad. It is worth mentioning that only less than 25% of the total supply of 3 billion SAND tokens were released publicly. SAND is a digital token backed by ERC-20 that can be traded on major exchanges. This is one of their 3D games that was made more successful by the acquisition of Pixowl back in 2018.Īnimoca global mobile game developer and publisher, last year launched a new ICO called SAND. The game first released in 2011 and was developed by Pixowl, who were founded by Sébastien Borget & Arthur Madrid. Technically, the game itself is called ‘The Sandbox’ and the token is simply called SAND, but most people use the ter The game ‘The Sandbox’ itself can also be called by this name, but most people simply call the token SAND. The Sandbox is a token that powers the decentralised virtual gaming platform. From Carmina’s tunneling glare, pregnant with a meaning we can deduce only individually, to obsessive New Age acolyte Andrea (Ainara Paredes) and her enthusiastic embrace of every new esoteric trend, the population of Elche is seen in a quest for guidance while continuing to value connections amongst themselves, whether in coffee klatches or group meetings. The final shot, of a giant inflating plastic Sphinx, its girth ultimately obscuring the important action behind, is a brilliant summation not just of what the story suggests - innocent madness can too easily distract from disturbing implications - but the director’s own talents.Īs with his award-winning shorts, Ibarra cast from local non-professionals whose distinctive physical characteristics add a crucial note of verisimilitude. It’s a risky calculation but one that pays off because Ibarra uses our discomfort to make us question the innocence of daft theories and how easy it is to take advantage of people searching for signs. When things take a darker turn and it becomes clear that Julio’s been taking advantage of the ufology group’s gullibility for his own pedophilic purposes, the film’s tone starts to feel uncomfortable, as if its puckish gaze isn’t distinguishing between eccentricity and depravity. While most of the people in “The Sacred Spirit” are demonstrably bonkers, there’s a sense that they’ve come to these ideas from a desire to be part of something greater than themselves. Ibarra never treats these characters and their beliefs with disdain, even if we inevitably chuckle at their theories. He was primed for such screwball notions by his leopard-print-loving mother Carmina (Rocío Ibáñez), a psychic whose sibylline pronouncements were taken as gospel by the neighborhood until Alzheimer’s reduced her capacity to make any sense. José Manuel’s unquestioning belief in such off-the-wall theories extends to other loony New Age esoterica, signaled by the ancient Egyptian motifs decorating the café he runs. A trusting, sweet girl, Verónica has reasons to imagine there are dark forces about since her twin sister Vanessa has gone missing and their mother Charo (Joanna Valverde) is appealing to the public through the local news station in their home city of Elche (also the director’s native town, in Alicante province).Ĭharo’s brother José Manuel (Nacho Fernández) is a member of a local ufology group meeting regularly in the real estate offices of their leader Julio (José Ángel Asensio), where they share information on alien visits and abductions from past and present. It’s at once ridiculous and disturbing: She’s barely school age and the subject is patently ludicrous, especially coming from the mouth of someone so young, but the seriousness of the delivery and the tight, fixed framing combine to generate a feeling of uneasy amusement that endures for the rest of the film. The tone is set right from the start when little Verónica (Llum Arqués) does an in-class presentation about how devil worshippers are involved in child organ trafficking. 5/4/2023 0 Comments Beyond a steel sky museum![]() Beneath a Steel Sky - Remastered was reviewed with version 1.0. It's just silly enough to make it entertaining. A lot of the vocals are on the same par as Greg Miller's impression of Rupert Murdoch. ![]() The most questionable elements of the production are the voice -overs they're incredibly hammy. There's no full animation during these sequences, but sort of still panels moving around on screen, and it gets the job done. They're redrawn by Dave Gibbons ("Watchmen"), providing really smart eye candy. The videos that fill in the narrative are easily the most obvious "remastered" element. Whether it's some sort of conveyor belt in the distance or just a catwalk across the way, it's really well done. In fact, the backgrounds are one of my high points in the game - there's always something going on. All of the backgrounds are detailed and a joy to look at. The visuals are an attractive update of the original release. They don't tell you exactly what to do, but they certainly point you in the right direction. You'll often find yourself simply tinkering around with everything in a given screen to see what it does until that moment when the current puzzle just "clicks." A lot of tasks require that you really pay attention to what's going on, but should you have missed a clue somewhere along the line, you can get hints in the menu screen. You're really encouraged to explore and experiment with the game world. It is a direct sequel to 1994's Beneath a Steel Sky and absolutely assumes you've already played that game. The interface is intuitive and responsive. Beyond a Steel Sky is a cyberpunk/sci-fi point and click adventure game developed and published in 2021 by Revolution Software (creators of the Broken Sword series). If there's something for you to use or see, tap that item and it springs into action. ![]() Beneath a Steel Sky is a great example of point-and-click adventure games like Monkey Island or Kings Quest. Without giving away too much, Foster eventually survives another chopper crash and finds himself smack dab in the middle of a tyrannical metropolis, with only his robot sidekick Joey by his side. However, it now seems that his past, whatever that may be, is coming back to haunt him. As a boy, he survived a helicopter crash, prompting locals to take him in and raise him as one of their own. |